uu.seUppsala University Publications
Change search
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • ieee
  • modern-language-association
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf
Time-resolved inner-shell photoelectron spectroscopy: From a bound molecule to an isolated atom
Max Born Inst Nichtlineare Opt & Kurzzeitspektros, D-12489 Berlin, Germany.
Max Born Inst Nichtlineare Opt & Kurzzeitspektros, D-12489 Berlin, Germany.
Univ Oxford, Dept Chem, Chem Res Lab, Oxford OX1 3TA, England.
DESY, D-22607 Hamburg, Germany.
Show others and affiliations
2018 (English)In: Physical Review A: covering atomic, molecular, and optical physics and quantum information, ISSN 2469-9926, E-ISSN 2469-9934, Vol. 97, no 4, article id 043429Article in journal (Refereed) Published
Abstract [en]

Due to its element and site specificity, inner-shell photoelectron spectroscopy is a widely used technique to probe the chemical structure of matter. Here, we show that time-resolved inner-shell photoelectron spectroscopy can be employed to observe ultrafast chemical reactions and the electronic response to the nuclear motion with high sensitivity. The ultraviolet dissociation of iodomethane (CH3I) is investigated by ionization above the iodine 4d edge, using time-resolved inner-shell photoelectron and photoion spectroscopy. The dynamics observed in the photoelectron spectra appear earlier and are faster than those seen in the iodine fragments. The experimental results are interpreted using crystal-field and spin-orbit configuration interaction calculations, and demonstrate that time-resolved inner-shell photoelectron spectroscopy is a powerful tool to directly track ultrafast structural and electronic transformations in gas-phase molecules.

Place, publisher, year, edition, pages
2018. Vol. 97, no 4, article id 043429
National Category
Atom and Molecular Physics and Optics
Identifiers
URN: urn:nbn:se:uu:diva-355468DOI: 10.1103/PhysRevA.97.043429ISI: 000431967800005OAI: oai:DiVA.org:uu-355468DiVA, id: diva2:1229274
Funder
EU, FP7, Seventh Framework Programme, 238671EU, Horizon 2020, 641789Swedish Research CouncilSwedish Foundation for Strategic Research German Research Foundation (DFG), RO 4577/1-1Available from: 2018-06-29 Created: 2018-06-29 Last updated: 2018-06-29Bibliographically approved

Open Access in DiVA

No full text in DiVA

Other links

Publisher's full text

Authority records BETA

Piancastelli, Maria Novella

Search in DiVA

By author/editor
Piancastelli, Maria Novella
By organisation
Department of Physics and AstronomyMolecular and Condensed Matter Physics
In the same journal
Physical Review A: covering atomic, molecular, and optical physics and quantum information
Atom and Molecular Physics and Optics

Search outside of DiVA

GoogleGoogle Scholar

doi
urn-nbn

Altmetric score

doi
urn-nbn
Total: 34 hits
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • ieee
  • modern-language-association
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf