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Alkynyl Coinage Metal Clusters and Complexes-Syntheses, Structures, and Strategies
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström.ORCID iD: 0000-0002-8969-1236
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Inorganic Chemistry.ORCID iD: 0000-0001-5403-9902
2018 (English)In: Chemistry - A European Journal, ISSN 0947-6539, E-ISSN 1521-3765, Vol. 24, no 30, p. 7536-+Article in journal (Refereed) Published
Abstract [en]

In this Concept we discuss how the chemistry of coinage metal complexes based on alkynyl ligands has developed over the past decades. The rich coordination of alkynyl, that exhibit both (1) (end-on) and (2) (side on) modes, includes non-bridged systems, as well as bridging of up to four (or six) metal centres. Resulting metal clusters often exhibit highly regular structures and typical coordination motifs forming fascinating assemblies exploiting this versatile coordination. Metallophilic interactions are often an important driving force for the formation of large clusters. In addition, the use of co-ligands as well the possibility to encapsulate counter ions greatly increases the chemical and structural diversity. Herein we attempt to summarize and highlight design principles towards multinuclear homo and hetero-bi-metallic coinage metal clusters of alkynyl ligands.

Place, publisher, year, edition, pages
Wiley-VCH Verlagsgesellschaft, 2018. Vol. 24, no 30, p. 7536-+
Keywords [en]
alkynyl ligands, cluster compounds, coinage metals, metallophilic interactions, X-ray crystallography
National Category
Materials Chemistry
Identifiers
URN: urn:nbn:se:uu:diva-357737DOI: 10.1002/chem.201704667ISI: 000434089500001PubMedID: 29390168OAI: oai:DiVA.org:uu-357737DiVA, id: diva2:1243230
Available from: 2018-08-30 Created: 2018-08-30 Last updated: 2018-10-05Bibliographically approved

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Gupta, Arvind KumarOrthaber, Andreas

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