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Hydrogen sorption in TiZrNbHfTa high entropy alloy
Univ Paris Est, Inst Chim & Mat Paris Est UMR7182, CNRS, UPEC, 2-8 Rue Henri Dunant, F-94320 Thiais, France.
Univ Paris Est, Inst Chim & Mat Paris Est UMR7182, CNRS, UPEC, 2-8 Rue Henri Dunant, F-94320 Thiais, France.
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Inorganic Chemistry.
Univ Paris Est, Inst Chim & Mat Paris Est UMR7182, CNRS, UPEC, 2-8 Rue Henri Dunant, F-94320 Thiais, France.
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2019 (English)In: Journal of Alloys and Compounds, ISSN 0925-8388, E-ISSN 1873-4669, Vol. 775, p. 667-674Article in journal (Refereed) Published
Abstract [en]

High Entropy Alloys (HEA), where five or more elements are mixed together in near equiatomic ratios offer promising properties as hydrogen storage materials due to their ability to crystallize in simple cubic structures in the presence of large lattice strain originating from the different sizes of the atoms. In this work, the hydrogen absorption and desorption as well as the cycling properties of the TiZrNbHfTa HEA have been studied by in situ Synchrotron X-Ray diffraction, Pressure-Composition-Isotherm, Thermal Desorption Spectroscopy and Differential Scanning Calorimetry. The alloy crystallizes in a cubic bcc phase and undergoes a two-stage hydrogen absorption reaction to a fcc dihydride phase with an intermediate tetragonal monohydride, very similar to the V-H system. The hydrogen absorption/desorption in TiZrNbHfTa is completely reversible and the activation energy of desorption could be calculated. Furthermore, we have observed an interesting macrostructure following parallel planes after the formation of the dihydride phase, which is retained after desorption.

Place, publisher, year, edition, pages
ELSEVIER SCIENCE SA , 2019. Vol. 775, p. 667-674
Keywords [en]
High entropy alloys, Hydrogen absorption/desorption, In situ synchrotron X-ray diffraction, Activation energy of hydrogen desorption
National Category
Materials Chemistry
Identifiers
URN: urn:nbn:se:uu:diva-372365DOI: 10.1016/j.jallcom.2018.10.108ISI: 000450981100079OAI: oai:DiVA.org:uu-372365DiVA, id: diva2:1277007
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NordForsk, 81942Available from: 2019-01-09 Created: 2019-01-09 Last updated: 2019-01-09Bibliographically approved

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Ek, GustavSahlberg, Martin

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