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Upon the photostability of 8-nitro-cGMP and its caging as a 7-dimethylaminocoumarinyl ester
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Polymer Chemistry.
Interfaculty Institute of Biochemistry, University of Tübingen, Auf der Morgenstelle 15, D-72076 Tübingen, Germany.
2014 (English)In: Chemical Communications, ISSN 1359-7345, E-ISSN 1364-548X, Vol. 50, p. 7120-7123Article in journal (Refereed) Published
Abstract [en]

8-Nitro-cGMP was recently discovered as a second messenger of nitric oxide. We describe here the synthesis and properties of DMACM-modified 8-nitro-cGMP for photochemical uncaging. Owing to the limited photostability of 8-nitro-cGMP care must be taken, but the photorelease of the intact product was readily feasible. Unexpectedly, 8-nitro-cGMP decays under formation of 8-nitrosoguanine when irradiated with light.

Place, publisher, year, edition, pages
2014. Vol. 50, p. 7120-7123
National Category
Biochemistry and Molecular Biology
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URN: urn:nbn:se:uu:diva-373483DOI: 10.1039/c4cc02828gOAI: oai:DiVA.org:uu-373483DiVA, id: diva2:1278620
Available from: 2019-01-14 Created: 2019-01-14 Last updated: 2019-08-07Bibliographically approved

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