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Pincer Complex-Catalyzed Redox Coupling of Alkenes with Iodonium Salts via Presumed Palladium(IV) Intermediates.
2009 (English)In: Organic Letters, ISSN 1523-7060, E-ISSN 1523-7052, Vol. 11, no 13, p. 2852-2854Article in journal (Refereed) Published
Abstract [en]

Palladium pincer complexes directly catalyze the redox coupling reactions of functionalized alkenes and iodonium salts. The catalytic process, which is suitable for mild catalytic functionalization of allylic acetates and electron-rich alkenes, probably occurs through Pd(IV) intermediates. Due to the strong metal-ligand interactions, the oxidn. of phosphine and amine ligands of the pincer complexes can be avoided in the presented reactions. [on SciFinder(R)]

Place, publisher, year, edition, pages
American Chemical Society , 2009. Vol. 11, no 13, p. 2852-2854
Keywords [en]
palladium pincer complex catalyst redox coupling alkene iodonium salt
National Category
Organic Chemistry
Identifiers
URN: urn:nbn:se:uu:diva-374755DOI: 10.1021/ol9010739OAI: oai:DiVA.org:uu-374755DiVA, id: diva2:1282032
Note

Copyright (C) 2019 American Chemical Society (ACS). All Rights Reserved.; CAPLUS AN 2009:652491(Journal)

Available from: 2019-01-23 Created: 2019-01-23 Last updated: 2019-01-23

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