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Effect of Arsenic Coordination State on the Structure, Aromaticity, and Optical Properties of Dithieno[3,2-b:2 ',3 '-d]arsoles
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström. (Syntetisk molekylär kemi)
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström. (Syntetisk molekylär kemi)ORCID iD: 0000-0002-8969-1236
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström. (Syntetisk molekylär kemi)ORCID iD: 0000-0001-5403-9902
2019 (English)In: European Journal of Inorganic Chemistry, ISSN 1434-1948, E-ISSN 1099-1948, no 11-12, p. 1539-1543Article in journal (Refereed) Published
Abstract [en]

A silylated derivative of 4-phenyl-dithieno[3,2-b:2 ',3 '-d]arsole (DTAs) was synthesized, and the effect of coordinating of DTAs compounds to Pd on their structural and optical properties was investigated. Coordination of the As to Pd was found to increase the structural aromaticity of the ring system as measured by the harmonic oscillator measure of heterocyclic electron delocalization (HOMHED), and the pyramidalization of the As atoms was also found to show a good correlation with the HOMHED values. However, coordination had a more subtle impact on the optical properties than seen for phosphorus-containing analogues as the metal-ligand interactions were weaker.

Place, publisher, year, edition, pages
2019. no 11-12, p. 1539-1543
Keywords [en]
Dithienoarsole, Aromaticity, Luminescence, Palladium complex, Arsenic
National Category
Inorganic Chemistry
Identifiers
URN: urn:nbn:se:uu:diva-381571DOI: 10.1002/ejic.201801169ISI: 000462351000012OAI: oai:DiVA.org:uu-381571DiVA, id: diva2:1304662
Funder
Swedish Research CouncilSwedish Energy AgencyCarl Tryggers foundation
Note

Correction in: Eur. J. Inorg. Chem. 2019, 1706

DOI: 10.1002/ejic.201900057

Available from: 2019-04-12 Created: 2019-04-12 Last updated: 2019-04-23Bibliographically approved

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Green, Joshua P.Gupta, Arvind KumarOrthaber, Andreas

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