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Solvent and Counter-Ion Induced Coordination Environment Changes Towards Ag-I Coordination Polymers
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Synthetic Molecular Chemistry.ORCID iD: 0000-0002-8969-1236
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Synthetic Molecular Chemistry.
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Synthetic Molecular Chemistry.ORCID iD: 0000-0001-5403-9902
2019 (English)In: European Journal of Inorganic Chemistry, ISSN 1434-1948, E-ISSN 1099-1948, Vol. 2019, no 33, p. 3740-3744Article in journal (Refereed) Published
Abstract [en]

A series of silver coordination polymers based on the 9,9 '-bis(4,5-diazafluorene) (BDF-H-2) ligand is presented. The choice of counterions and reaction conditions dictate the observed topology on the final systems by influencing the silver coordination environment. Coordination modes, flexibility of the ligand and extended pi-pi stacking interactions have allowed the preparation and crystallographic characterisation of one 1D- and three 2D-coordination polymers: 1D-[Ag(BDF-H-2)(DMSO)](n)(X)(n) (where X = OTf- and ClO4-); 1D-[Ag-2(BDF-H-2) m(1)-(TfO)(2),m(2)-(TfO)(2)](n)(TfO)(n), and 2D-[Ag-2(BDF-H-2)(3)](n)(PF6)(2n).

Place, publisher, year, edition, pages
WILEY-V C H VERLAG GMBH , 2019. Vol. 2019, no 33, p. 3740-3744
Keywords [en]
Coordination polymers, Diazafluorenes, Solvent effects, Silver, Topology
National Category
Inorganic Chemistry
Identifiers
URN: urn:nbn:se:uu:diva-396120DOI: 10.1002/ejic.201900722ISI: 000478937600001OAI: oai:DiVA.org:uu-396120DiVA, id: diva2:1366788
Available from: 2019-10-30 Created: 2019-10-30 Last updated: 2019-10-30Bibliographically approved

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Gupta, Arvind KumarMorales Salazar, DanielOrthaber, Andreas

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