Thermo-elastic behavior of hexagonal Sc-Ti-Zr-Hf high-entropy alloysShow others and affiliations
2022 (English)In: Journal of Physics D: Applied Physics, ISSN 0022-3727, E-ISSN 1361-6463, Vol. 55, no 23, article id 235302Article in journal (Refereed) Published
Abstract [en]
Recent advances in tuning the long-standing strength-ductility tradeoff have drawn attention to high-entropy alloys (HEAs), and the appearance of hexagonal close-packed (hcp) structures has been emphasized. However, few studies have explored the elastic moduli of hcp HEAs, which is of prime importance for improved understanding of the outstanding mechanical properties. In this work, we focus on a set of equiatomic rare-earth-free HEAs with hcp structures, i.e. ScTiZr, ScTiHf, ScZrHf, TiZrHf, and ScTiZrHf, and their thermo-elastic properties are studied using quantum mechanical first-principles methods. It is found that, for all considered HEAs, the hexagonal axial ratio shows a weak dependence on the temperature effect, and the thermal expansion coefficient remains almost unchanged above room temperature. From the calculated temperature-dependent single-crystal elastic constants, we analyzed the mechanical stability, elastic anisotropy, and derived polycrystalline moduli. Results indicate that the present HEAs exhibit rather high elastic isotropy and large elastic softening resistance. The ab initio predicted Young's modulus, shear modulus, and specific modulus do not obey the rule of mixture, which indicates that there exists a strong intrinsic hardening effect in all of the considered HEAs. The calculated results are in good agreement with the available experimental measurements.
Place, publisher, year, edition, pages
IOP Publishing Institute of Physics (IOP), 2022. Vol. 55, no 23, article id 235302
Keywords [en]
high-entropy alloys, hexagonal crystals, elastic constants, thermal expansion, ab-initio calculations
National Category
Condensed Matter Physics
Identifiers
URN: urn:nbn:se:uu:diva-470566DOI: 10.1088/1361-6463/ac50ceISI: 000767558500001OAI: oai:DiVA.org:uu-470566DiVA, id: diva2:1647703
Funder
Swedish Foundation for Strategic Research Swedish Research CouncilVinnova, 2019-051112022-03-282022-03-282024-12-03Bibliographically approved