Logo: to the web site of Uppsala University

uu.sePublications from Uppsala University
Change search
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • ieee
  • modern-language-association
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf
Ultrafast dissociation of ammonia: Auger Doppler effect and redistribution of the internal energy
Sorbonne Univ, Lab Chim Phys Matiere & Rayonnement, CNRS, UMR 7614, F-75005 Paris, France..ORCID iD: 0000-0001-9504-3692
Univ Turku, Dept Phys & Astron, FI-20014 Turku, Finland..
Sorbonne Univ, Lab Chim Phys Matiere & Rayonnement, CNRS, UMR 7614, F-75005 Paris, France.;Synchrotron SOLEIL, F-91192 Gif Sur Yvette, France..
Univ Turku, Dept Phys & Astron, FI-20014 Turku, Finland..
Show others and affiliations
2022 (English)In: Physical Chemistry, Chemical Physics - PCCP, ISSN 1463-9076, E-ISSN 1463-9084, Vol. 24, no 10, p. 5842-5854Article in journal (Refereed) Published
Abstract [en]

We study vibrationally-resolved resonant Auger (RAS) spectra of ammonia recorded in coincidence with the NH2+ fragment, which is produced in the course of dissociation either in the core-excited 1s(-1)4a1(1) intermediate state or the first spectator 3a(-2)4a1(1) final state. Correlation of the NH2+ ion flight times with electron kinetic energies allows directly observing the Auger-Doppler dispersion for each vibrational state of the fragment. The median distribution of the kinetic energy release E-KER, derived from the coincidence data, shows three distinct branches as a function of Auger electron kinetic energy E-e: E-e + 1.75E(KER) = const for the molecular band; E-KER = const for the fragment band; and E-e + E-KER = const for the region preceding the fragment band. The deviation of the molecular band dispersion from E-e + E-KER = const is attributed to the redistribution of the available energy to the dissociation energy and excitation of the internal degrees of freedom in the molecular fragment. We found that for each vibrational line the dispersive behavior of E(KER)vs. E-e is very sensitive to the instrumental uncertainty in the determination of E-KER causing the competition between the Raman (E-KER + E-e = const) and Auger (E-e = const) dispersions: increase in the broadening of the finite kinetic energy release resolution leads to a change of the dispersion from the Raman to the Auger one.

Place, publisher, year, edition, pages
Royal Society of Chemistry, 2022. Vol. 24, no 10, p. 5842-5854
National Category
Physical Chemistry Atom and Molecular Physics and Optics
Identifiers
URN: urn:nbn:se:uu:diva-485649DOI: 10.1039/d1cp05499fISI: 000759750400001PubMedID: 35195639OAI: oai:DiVA.org:uu-485649DiVA, id: diva2:1701418
Funder
Swedish Research Council, 2018-07152Swedish Research Council, 2019-03470Vinnova, 2018-04969Swedish Research Council Formas, 2019-02496Available from: 2022-10-05 Created: 2022-10-05 Last updated: 2022-10-05Bibliographically approved

Open Access in DiVA

No full text in DiVA

Other links

Publisher's full textPubMed

Authority records

Piancastelli, Maria Novella

Search in DiVA

By author/editor
Travnikova, OksanaMarchenko, TatianaIsmail, IyasJournel, LoicPiancastelli, Maria Novella
By organisation
Department of Physics and Astronomy
In the same journal
Physical Chemistry, Chemical Physics - PCCP
Physical ChemistryAtom and Molecular Physics and Optics

Search outside of DiVA

GoogleGoogle Scholar

doi
pubmed
urn-nbn

Altmetric score

doi
pubmed
urn-nbn
Total: 30 hits
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • ieee
  • modern-language-association
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf