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Hysteresis-Free Planar Perovskite Solar Module with 19.1% Efficiency by Interfacial Defects Passivation
Univ Roma Tor Vergata, CHOSE Ctr Hybrid & Organ Solar Energy, Dept Elect Engn, Via Politecn 1, I-00133 Rome, Italy..ORCID iD: 0000-0003-3322-8688
Univ Roma Tor Vergata, CHOSE Ctr Hybrid & Organ Solar Energy, Dept Elect Engn, Via Politecn 1, I-00133 Rome, Italy..
Univ Roma Tor Vergata, CHOSE Ctr Hybrid & Organ Solar Energy, Dept Elect Engn, Via Politecn 1, I-00133 Rome, Italy..
IMEC Partner EnergyVille & Solliance, Thin Film PV, IMEC, Thor Pk 8320, B-3600 Genk, Belgium..
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2022 (English)In: Solar RRL, E-ISSN 2367-198X, Vol. 6, no 7, article id 2101095Article in journal (Refereed) Published
Abstract [en]

In few years, perovskite solar devices have reached high efficiency on lab scale cells. Upscaling to module size, effective perovskite recipe and posttreatment are of paramount importance to the breakthrough of the technology. Herein this work, the development of a low-temperature planar n-i-p perovskite module (11 cm(2) aperture area, 91% geometrical fill factor) is reported on, exploiting the defect passivation strategy to achieve an efficiency of 19.1% (2% losses stabilized) with near-zero hysteresis, that is the most unsolved issue in the perovskite photovoltaic technology. The I/Br (iodine/bromide) halide ion ratio of the triple-cation perovskite formulation and deposition procedure are optimized to move from small area to module device and to avoid the detrimental effect of dimethyl sulfoxide (DMSO) solvent. The organic halide salt phenethylammonium iodide (PEAI) is adopted as surface passivation material on module size to suppress perovskite defects. Finally, homogeneous and defect-free layers from cell to module with only 8% relative efficiency losses, high reproducibility, and optimized interconnections are scaled by laser ablation methods. The homogeneity of the perovskite layers and of the full stack was assessed by optical, morphological, and light beam-induced current (LBIC) mapping characterizations.

Place, publisher, year, edition, pages
John Wiley & Sons, 2022. Vol. 6, no 7, article id 2101095
Keywords [en]
high efficiency, module upscaling, passivation, perovskite photovoltaics
National Category
Physical Chemistry Materials Chemistry
Identifiers
URN: urn:nbn:se:uu:diva-485644DOI: 10.1002/solr.202101095ISI: 000779885300001OAI: oai:DiVA.org:uu-485644DiVA, id: diva2:1701631
Funder
EU, Horizon 2020, 691664Available from: 2022-10-06 Created: 2022-10-06 Last updated: 2022-10-06Bibliographically approved

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Yang, BowenSuo, JiajiaHagfeldt, Anders

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