Modulation and binding properties of extended glycoluril molecular clips
2008 (English)In: New Journal of Chemistry, ISSN 1144-0546, E-ISSN 1369-9261, Vol. 32, no 4, 643-651 p.Article in journal (Refereed) Published
A glycoluril clip (1) provides a deep cavity for binding of guest molecules. Guest species interact preferentially via hydrogen bonding or ion - lone pair interactions. Complexation-induced conformational modulation of the cavity wall distance was observed. At higher guest - host ratios, inclusion compounds with organic guest molecules are obtained. The X-ray crystallographic structure of 1 center dot(NH4PF6) center dot 3CHCl(3) center dot 2CH(3)OH shows formation of a network of clips connected via polar and non-polar interactions.
Place, publisher, year, edition, pages
2008. Vol. 32, no 4, 643-651 p.
IdentifiersURN: urn:nbn:se:uu:diva-96238DOI: 10.1039/b715208fISI: 000254634300008OAI: oai:DiVA.org:uu-96238DiVA: diva2:170744