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Manifestation of postcollision interaction in Krypton LMN Auger spectra following K-shell photoionization
Argonne Natl Lab, Chem Sci & Engn Div, Lemont, IL 60439 USA..
Argonne Natl Lab, Chem Sci & Engn Div, Lemont, IL 60439 USA.;Univ Hamburg, Ctr Free Electron Laser Sci, Luruper Chaussee 149, D-22761 Hamburg, Germany.;Univ Hamburg, Dept Phys, Luruper Chaussee 149, D-22761 Hamburg, Germany..
Argonne Natl Lab, Chem Sci & Engn Div, Lemont, IL 60439 USA..
Argonne Natl Lab, Chem Sci & Engn Div, Lemont, IL 60439 USA..
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2022 (English)In: Physical Review A: covering atomic, molecular, and optical physics and quantum information, ISSN 2469-9926, E-ISSN 2469-9934, Vol. 106, no 2, article id 023110Article in journal (Refereed) Published
Abstract [en]

We report on an experimental and theoretical study of postcollision interaction (PCI) effects on L-2 - M4,5N2,3 Auger electrons measured above the Kr K-edge in which L-2 vacancies are primarily generated by KL2 x-ray emission. Such cascade processes, in which a deep inner-shell vacancy decays first by x-ray emission followed by Auger electron emission, is a strong decay mode in heavy atoms. The L-2 - M4,5N2,3 Auger electron peak is observed to become increasingly asymmetric with a shifting peak maximum as the absorbed x-ray energy approaches the K-shell ionization threshold. This is attributed to PCI energy exchanges of the Auger electron with the 1s photoelectron. To model the PCI effects, we have applied a semiclassical approach modified to account for the combined lifetimes of the K and L-2 hole states. In addition, our analysis treats several closely spaced Auger transitions with final ionic states having different terms and angular momenta.

Place, publisher, year, edition, pages
American Physical Society, 2022. Vol. 106, no 2, article id 023110
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Atom and Molecular Physics and Optics
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URN: urn:nbn:se:uu:diva-490005DOI: 10.1103/PhysRevA.106.023110ISI: 000884776200008OAI: oai:DiVA.org:uu-490005DiVA, id: diva2:1717007
Available from: 2022-12-07 Created: 2022-12-07 Last updated: 2023-02-13Bibliographically approved

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Piancastelli, Maria Novella

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