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Search for superconductivity in hydrides of TiZrNb, TiZrNbHf and TiZrNbHfTa equimolar alloys
Slovak Acad Sci, Ctr Low Temp Phys, Inst Expt Phys, Watsonova 47, SK-04001 Kosice, Slovakia..
Stockholm Univ, Dept Mat & Environm Chem, SE-10691 Stockholm, Sweden..
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Structural Chemistry.ORCID iD: 0000-0003-4831-3842
Slovak Acad Sci, Ctr Low Temp Phys, Inst Expt Phys, Watsonova 47, SK-04001 Kosice, Slovakia..
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2023 (English)In: Physica. B, Condensed matter, ISSN 0921-4526, E-ISSN 1873-2135, Vol. 648, article id 414414Article in journal (Refereed) Published
Abstract [en]

We have prepared and investigated the superconducting equimolar alloys TiZrNb, TiZrNbHf and TiZrNbHfTa, which exhibit transition temperatures Tc between 6.4 K and 8.4 K, and examined the influence of hydrogenation on their superconductivity. The upper critical magnetic field Hc2 of alloys was estimated to be above 10 T, in agreement with previous studies of superconducting alloys of similar composition. On the other hand, the hy-drogenation of alloys, some of which appear to be promising for hydrogen storage, lead to suppression of su-perconductivity in TiZrNb, TiZrNbHf and TiZrNbHfTa dihydrides and in TiZrNbHfTa monohydride, and no transition to superconducting state was observed therein above 2 K. A possible reason for this may be related to the high concentration of disorder (defects) in hydrides originating from the preparation method during which the starting alloy disintegrates into fine powder.

Place, publisher, year, edition, pages
Elsevier, 2023. Vol. 648, article id 414414
Keywords [en]
Superconductivity, High-entropy alloy, Medium-entropy alloy, Hydrogenation, Superconductivity suppression
National Category
Condensed Matter Physics
Identifiers
URN: urn:nbn:se:uu:diva-490542DOI: 10.1016/j.physb.2022.414414ISI: 000886098000001OAI: oai:DiVA.org:uu-490542DiVA, id: diva2:1719613
Funder
Swedish Research Council, 2019-00645Available from: 2022-12-15 Created: 2022-12-15 Last updated: 2022-12-15Bibliographically approved

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