Dynamic ligation at the first amine-coordinated iron hydrogenase active site mimic
2006 (English)In: Chemical Communications, ISSN 1359-7345, E-ISSN 1364-548X, no 40, 4206-4208 p.Article in journal (Refereed) Published
The first model of the iron hydrogenase active site has been prepared in which an amine ligand is loosely coordinated to an Fe-I centre, and can be replaced by a solvent molecule; irrespective of the ligand set, the one electron reduction of both complexes is chemically reversible and is shown to proceed through the same species which features a bridging CO ligand.
Place, publisher, year, edition, pages
2006. no 40, 4206-4208 p.
IdentifiersURN: urn:nbn:se:uu:diva-98034DOI: 10.1039/b608260bISI: 000241582100012OAI: oai:DiVA.org:uu-98034DiVA: diva2:173197