Influence of an electron-deficient bridging o-carborane on the electronic properties of an [FeFe] hydrogenase active site model
2008 (English)In: Dalton Transactions, ISSN 1477-9226, no 18, 2379-2381 p.Article in journal (Refereed) Published
The IR carbonyl stretching frequencies of [Fe-2(SRS)(CO)(6)] complexes correlate well with their first reduction potential; an [FeFe] hydrogenase model with a very mild reduction potential has been realized by using a strongly electron deficient carborane-dithiolate bridge.
Place, publisher, year, edition, pages
2008. no 18, 2379-2381 p.
IdentifiersURN: urn:nbn:se:uu:diva-98036DOI: 10.1039/b802908nISI: 000255599000002OAI: oai:DiVA.org:uu-98036DiVA: diva2:173199