Aminocarbonylations of Alkenyl Phosphates, Chlorides, Bromides and Triflates with Mo(CO)6 as a Solid CO source
2009 (English)In: Tetrahedron, ISSN 0040-4020, E-ISSN 1464-5416, Vol. 65, no 36, 7646-7652 p.Article in journal (Refereed) Published
Palladium-catalyzed aminocarbonylations of alkenyl chlorides, bromides, and triflates were investigated using Mo(CO)6 as a solid carbon monoxide source. The reactions afforded moderate to good yields producing a wide variety of acrylamides after 20 minutes of microwave irradiation. In addition, the aminocarbonylation reaction was, for the first time, expanded to include alkenyl phosphates as starting materials.
Place, publisher, year, edition, pages
2009. Vol. 65, no 36, 7646-7652 p.
Carbonylation, Microwave, Vinyl halides, Vinyl phosphates, Vinyl triflates, Alkenyl electrophiles, Palladium, Enolizable ketones
IdentifiersURN: urn:nbn:se:uu:diva-100358DOI: 10.1016/j.tet.2009.06.101ISI: 000269340000043OAI: oai:DiVA.org:uu-100358DiVA: diva2:210167