Microwave-promoted aminocarbonylation of aryl triflates using Mo(CO)(6) as a solid CO source
2008 (English)In: Tetrahedron Letters, ISSN 0040-4039, E-ISSN 1873-3581, Vol. 49, no 42, 6115-6118 p.Article in journal (Refereed) Published
Palladium-catalyzed carbonylations of aryl triflates with a range of nucleophiles using Mo(CO)(6) as a solid CO source were explored. The reactions proceeded smoothly providing moderate to good yields of the corresponding aryl amides, esters, or acylsulfonamides after only 20 min of microwave irradiation. The acyl transfer reagent 4-dimethylaminopyridine was found to promote some of the more difficult transformations. (C) 2008 Elsevier Ltd. All rights reserved.
Place, publisher, year, edition, pages
2008. Vol. 49, no 42, 6115-6118 p.
carbonylation, microwave, palladium, aryl triflate, DMAP
IdentifiersURN: urn:nbn:se:uu:diva-104379DOI: 10.1016/j.tetlet.2008.08.014ISI: 000259883800024ISBN: 0040-4039OAI: oai:DiVA.org:uu-104379DiVA: diva2:219718