uu.seUppsala University Publications
Change search
ReferencesLink to record
Permanent link

Direct link
Double photoionization and dication fragmentation of CF3I: Experiment and theory
Uppsala University, Disciplinary Domain of Science and Technology, Physics, Department of Physics and Materials Science, Soft X-Ray Physics.
2008 (English)In: Journal of Chemical Physics, ISSN 0021-9606, Vol. 128, no 23, 234303- p.Article in journal (Refereed) Published
Abstract [en]

The double photoionization of CF3I and the electronic structure and the dissociation dynamics of the CF3I++ dication have been investigated using large ab initio calculations and coincidence techniques. The double photoionization spectrum of CF3I consists of a continuous background with a number of narrow bands superimposed. The spectrum is attributed here to the population of groups of close lying electronic states interacting mutually by spin-orbit, spin-spin, and rovibronic couplings. At energies near the vertical double ionization threshold, CF3++I+ ionic fragments are produced. At higher energies, a very specific dissociation with double charge retained on one fragment, CF3I++-> , CF2I+++F becomes dominant and is attributed to a specific group of dication electronic states.

Place, publisher, year, edition, pages
2008. Vol. 128, no 23, 234303- p.
National Category
Physical Sciences
URN: urn:nbn:se:uu:diva-106247DOI: 10.1063/1.2937901ISI: 000256936700011OAI: oai:DiVA.org:uu-106247DiVA: diva2:224312
Available from: 2009-06-17 Created: 2009-06-17 Last updated: 2009-10-30Bibliographically approved

Open Access in DiVA

No full text

Other links

Publisher's full text
By organisation
Soft X-Ray Physics
In the same journal
Journal of Chemical Physics
Physical Sciences

Search outside of DiVA

GoogleGoogle Scholar
The number of downloads is the sum of all downloads of full texts. It may include eg previous versions that are now no longer available

Altmetric score

Total: 167 hits
ReferencesLink to record
Permanent link

Direct link