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The role of colloid formation in the photoinduced H2 production with a RuII-PdII supramolecular complex: A study by GC, XPS, and TEM
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Photochemistry and Molecular Science.
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Photochemistry and Molecular Science.
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2008 (English)In: Journal of the American Chemical Society, ISSN 0002-7863, E-ISSN 1520-5126, Vol. 130, no 1, 26-27 p.Article in journal (Refereed) Published
Abstract [en]

The dinuclear Run(II)-Pd-II complex shows efficient H-2 production in the presence of triethylamine as a sacrificial electron and proton donor under visible light irradiation. XPS and TEM analyses reveal that photoreduction of Pd-II to Pd-0 causes dissociation of Pd from the complex to form colloids that are suggested to be the actual catalyst for H-2 production.

Place, publisher, year, edition, pages
2008. Vol. 130, no 1, 26-27 p.
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Chemical Sciences
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URN: urn:nbn:se:uu:diva-113032DOI: 10.1021/ja0776780ISI: 000252127500013OAI: oai:DiVA.org:uu-113032DiVA: diva2:289705
Available from: 2010-01-25 Created: 2010-01-25 Last updated: 2016-04-20

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Lomoth, ReinerRensmo, Håkan

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