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Aminophosphonates as organocatalysts in the direct asymmetric aldol reaction: towards syn selectivity in the presence of Lewis bases
Organic Chemistry, Department of Chemistry, Göteborg University.
2006 (English)In: Organic and biomolecular chemistry, ISSN 1477-0520, E-ISSN 1477-0539, Vol. 4, no 11, 2091-2096 p.Article in journal (Refereed) Published
Abstract [en]

Chiral alpha-aminophosphonates have been synthesized and their performance was evaluated as organocatalysts in the direct asymmetric aldol reaction. High enantioselectivities (up to 99% ee) were achieved for a range of substituted cyclohexanones and benzaldehydes. Several organic bases, such as DBU, DBN, and TMG, were used together with the alpha-aminophosphonates in the aldol reactions and were found to favor syn-selectivity.

Place, publisher, year, edition, pages
2006. Vol. 4, no 11, 2091-2096 p.
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Chemical Sciences
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URN: urn:nbn:se:uu:diva-121907DOI: 10.1039/b605091cISI: 000237907500006PubMedID: 16729122OAI: oai:DiVA.org:uu-121907DiVA: diva2:306907
Available from: 2010-03-31 Created: 2010-03-31 Last updated: 2017-12-12Bibliographically approved

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Dinér, Peter

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