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Solution structure of a seven coordinated manganese(II) complex via electrospray ionization mass spectrometry
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Physical and Analytical Chemistry, Analytical Chemistry.
2010 (English)In: Spectrochimica Acta Part A - Molecular and Biomolecular Spectroscopy, ISSN 1386-1425, Vol. 75, no 3, 1168-1170 p.Article in journal (Refereed) Published
Abstract [en]

The mononuclear complex [Mn(tptz)(CH3COO)(OH2)2]NO3 (1) was investigated by electrospray ionization mass spectrometry in aqueous solution at pH 4.5. Electrospray ionization mass spectrometry shows that mononuclear and dinuclear manganese cationic species are present in solution, probably in equilibrium with neutral 1. An experiment showed that the most important reaction in the presence of oxone (2KHSO5·KHSO4·K2SO4) is decoordination.

Place, publisher, year, edition, pages
2010. Vol. 75, no 3, 1168-1170 p.
Keyword [en]
Manganese, Oxygen evolving complex, ESI(+)-MS/MS, tptz
National Category
Chemical Sciences
Research subject
Analytical Chemistry
URN: urn:nbn:se:uu:diva-122406DOI: 10.1016/j.saa.2009.12.086ISI: 000275584000036PubMedID: 20096625OAI: oai:DiVA.org:uu-122406DiVA: diva2:310026
Available from: 2010-04-12 Created: 2010-04-12 Last updated: 2011-07-08Bibliographically approved

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Sjöberg, Per J.R.
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