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(I,0) Mixed-Valence State of a Diiron Complex with Pertinence to the [FeFe]-Hydrogenase Active Site: An IR, EPR, and Computational Study
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Photochemistry and Molecular Science.
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Photochemistry and Molecular Science.
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Photochemistry and Molecular Science.
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Photochemistry and Molecular Science.
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2009 (English)In: Inorganic Chemistry, ISSN 0020-1669, E-ISSN 1520-510X, Vol. 48, no 23, 10883-10885 p.Article in journal (Refereed) Published
Abstract [en]

Biphenyl-2,2'-dithiolate (bpdt) bridged Fe-2(bpdt)(CO)(6) (1) undergoes two sequential electrochemically quasi-reversible reductions. The one-electron reduction product 1(-) is unusually stable against irreversible structural changes and could be characterized by IR and EPR spectroscopy supported by computational methods. Reduction to the (I,0) state does not trigger bridging coordination of CO but partial deligation of the dithiolate in 1(-) that ultimately forms a diamagnetic dimerization product.

Place, publisher, year, edition, pages
2009. Vol. 48, no 23, 10883-10885 p.
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Chemical Sciences
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URN: urn:nbn:se:uu:diva-127401DOI: 10.1021/ic9016454ISI: 000272037500010OAI: oai:DiVA.org:uu-127401DiVA: diva2:329859
Available from: 2010-07-14 Created: 2010-07-13 Last updated: 2017-12-12Bibliographically approved

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Lomoth, Reiner

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