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Exploitation of an unprecedented silica-promoted acetylene-allene rearrangement for the preparation of C,C-diacetylenic phosphaalkenes
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Photochemistry and Molecular Science.
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Photochemistry and Molecular Science.
2009 (English)In: Chemical Communications, ISSN 1359-7345, E-ISSN 1364-548X, no 46, 7206-7208 p.Article in journal (Refereed) Published
Abstract [en]

C,C-Diacetylenic phosphaalkenes have been obtained from a 1-chloro-3-ethynyl-1,2-allene which becomes accessible from a silica-promoted rearrangement of a 3-chloropenta-1,4-diyne; oxidative acetylene homo-coupling of the phosphadiethynyl-ethene is described for the first time and affords a dimeric, cross-conjugated product which features a largely decreased HOMO-LUMO gap compared to all-carbon-based reference compounds.

Place, publisher, year, edition, pages
2009. no 46, 7206-7208 p.
National Category
Chemical Sciences
Identifiers
URN: urn:nbn:se:uu:diva-127405DOI: 10.1039/b916640hISI: 000271907000037OAI: oai:DiVA.org:uu-127405DiVA: diva2:329863
Available from: 2010-07-14 Created: 2010-07-13 Last updated: 2017-12-12Bibliographically approved

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