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FTIR study on the light sensitivity of the [NiFe] hydrogenase from Desulfovibrio vulgaris Miyazaki F: Ni-C to Ni-L photoconversion, kinetics of proton rebinding and H/D isotope effect
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Photochemistry and Molecular Science.
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2009 (English)In: Physical Chemistry, Chemical Physics - PCCP, ISSN 1463-9076, E-ISSN 1463-9084, Vol. 11, no 39, 8680-8683 p.Article in journal (Refereed) Published
Abstract [en]

The light-induced Ni-C to Ni-L transition results in the dissociation of a hydrogenic species, originating from the dihydrogen splitting at the active site. Back conversion in the dark to form Ni-C was investigated by studying the rebinding kinetics of this ligand in protonated (H-2/H2O) and deuterated (D-2/D2O) samples using time resolved FTIR spectroscopy.

Place, publisher, year, edition, pages
2009. Vol. 11, no 39, 8680-8683 p.
National Category
Chemical Sciences
URN: urn:nbn:se:uu:diva-127495DOI: 10.1039/b913635eISI: 000270319600003OAI: oai:DiVA.org:uu-127495DiVA: diva2:330436
Available from: 2010-07-15 Created: 2010-07-13 Last updated: 2010-07-15Bibliographically approved

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