FTIR study on the light sensitivity of the [NiFe] hydrogenase from Desulfovibrio vulgaris Miyazaki F: Ni-C to Ni-L photoconversion, kinetics of proton rebinding and H/D isotope effect
2009 (English)In: Physical Chemistry, Chemical Physics - PCCP, ISSN 1463-9076, E-ISSN 1463-9084, Vol. 11, no 39, 8680-8683 p.Article in journal (Refereed) Published
The light-induced Ni-C to Ni-L transition results in the dissociation of a hydrogenic species, originating from the dihydrogen splitting at the active site. Back conversion in the dark to form Ni-C was investigated by studying the rebinding kinetics of this ligand in protonated (H-2/H2O) and deuterated (D-2/D2O) samples using time resolved FTIR spectroscopy.
Place, publisher, year, edition, pages
2009. Vol. 11, no 39, 8680-8683 p.
IdentifiersURN: urn:nbn:se:uu:diva-127495DOI: 10.1039/b913635eISI: 000270319600003OAI: oai:DiVA.org:uu-127495DiVA: diva2:330436