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Structure and Bonding of Ethylene Oxide on Si(100)
Uppsala University, Disciplinary Domain of Science and Technology, Physics, Department of Physics and Materials Science, Surface and Interface Science.
Uppsala University, Disciplinary Domain of Science and Technology, Physics, Department of Physics and Materials Science, Surface and Interface Science.
Uppsala University, Disciplinary Domain of Science and Technology, Physics, Department of Physics and Materials Science, Surface and Interface Science.
2009 (English)In: The Journal of Physical Chemistry C, ISSN 1932-7447, E-ISSN 1932-7455, Vol. 113, no 36, 16077-16082 p.Article in journal (Refereed) Published
Abstract [en]

The bonding configuration and electronic structure of ethylene oxide adsorbed on Si(100)-(2 x 1) is investigated with fully polarization resolved X-ray absorption spectroscopy as well as with core level and valence band photoemission spectroscopy. Ethylene oxide is found to adsorb via a ring-opening reaction, where the molecule forms a five-membered ring together with the silicon surface dimer atoms inserting between a carbon and the oxygen atom. In the resulting geometry, the molecule is tilted out of the surface plane.

Place, publisher, year, edition, pages
2009. Vol. 113, no 36, 16077-16082 p.
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Physical Sciences
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URN: urn:nbn:se:uu:diva-128268DOI: 10.1021/jp9030859ISI: 000269654700046OAI: oai:DiVA.org:uu-128268DiVA: diva2:331040
Available from: 2010-07-21 Created: 2010-07-20 Last updated: 2017-12-12

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Hennies, F

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