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B-Alkylcatecholborane-Mediated Tandem Radical Conjugated Addition-Aldol Cyclization
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Biochemistry and Organic Chemistry.
2009 (English)In: Organic Letters, ISSN 1523-7060, E-ISSN 1523-7052, Vol. 11, no 16, 3778-3781 p.Article in journal (Refereed) Published
Abstract [en]

A one-pot procedure involving radical conjugate addition of B-alkylcatecholboranes to enones followed by intramolecular aldol reaction is reported. Application to the stereoselective synthesis of monocyclic and bicyclic products with up to four contiguous stereogenic centers is presented.

Place, publisher, year, edition, pages
2009. Vol. 11, no 16, 3778-3781 p.
National Category
Chemical Sciences
Identifiers
URN: urn:nbn:se:uu:diva-128313DOI: 10.1021/ol9014943ISI: 000268796700065OAI: oai:DiVA.org:uu-128313DiVA: diva2:331171
Available from: 2010-07-21 Created: 2010-07-20 Last updated: 2017-12-12Bibliographically approved

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