uu.seUppsala University Publications
Change search
ReferencesLink to record
Permanent link

Direct link
Shake-up transitions in S 2p, S 2s and F 1s photoionization of the SF6 molecule
Show others and affiliations
2009 (English)In: Journal of Physics B: Atomic, Molecular and Optical Physics, ISSN 0953-4075, E-ISSN 1361-6455, Vol. 42, no 5, 055102- p.Article in journal (Refereed) Published
Abstract [en]

Shake-up transitions occurring upon core photoionization in the SF6 molecule have been studied experimentally and theoretically. The S 2p, S 2s and F 1s shake-up satellite photoelectron spectra were measured using A1 Ka radiation at 1487 eV photon energy. They have been interpreted with the aid of ab initio configuration interaction calculations in the sudden-limit approximation. For the S 2p spectrum, conjugate shake-up transitions were also calculated. Clear evidence of conjugate processes is observed in the S 2p shake-up spectrum measured at 230 eV photon energy. The experimental and theoretical S 2p and S 2s shake-up spectra show very similar structures mainly due to orbital relaxation involving S 3s and 3p participation. For the calculation of the F 1s shake-up spectrum, the symmetry lowering of the molecule in the final states was considered, resulting in a good agreement with the experiment.

Place, publisher, year, edition, pages
2009. Vol. 42, no 5, 055102- p.
National Category
Physical Sciences
URN: urn:nbn:se:uu:diva-130025DOI: 10.1088/0953-4075/42/5/055102ISI: 000263600900006OAI: oai:DiVA.org:uu-130025DiVA: diva2:345882
Available from: 2010-08-27 Created: 2010-08-27 Last updated: 2010-08-27Bibliographically approved

Open Access in DiVA

No full text

Other links

Publisher's full text
By organisation
Department of Physics
In the same journal
Journal of Physics B: Atomic, Molecular and Optical Physics
Physical Sciences

Search outside of DiVA

GoogleGoogle Scholar
The number of downloads is the sum of all downloads of full texts. It may include eg previous versions that are now no longer available

Altmetric score

Total: 162 hits
ReferencesLink to record
Permanent link

Direct link