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Iridium-catalyzed asymmetric hydrogenation of olefins using TIQ phosphine-oxazoline ligands
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Biochemistry and Organic Chemistry.
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2010 (English)In: Tetrahedron: asymmetry, ISSN 0957-4166, E-ISSN 1362-511X, Vol. 21, no 18, 2295-2301 p.Article in journal (Refereed) Published
Abstract [en]

A novel family of tetrahydroisoquinoline (TIQ) phosphine-oxazoline ligands and four corresponding iridium complexes have been developed and applied to the asymmetric hydrogenation of unfunctionalized olefins. The results showed that the best conversion rates were observed in up to 99% with an enantiomeric excess of 91%.

Place, publisher, year, edition, pages
2010. Vol. 21, no 18, 2295-2301 p.
National Category
Chemical Sciences
URN: urn:nbn:se:uu:diva-133578DOI: 10.1016/j.tetasy.2010.07.032ISI: 000282926600018OAI: oai:DiVA.org:uu-133578DiVA: diva2:370320
Available from: 2010-11-16 Created: 2010-11-11 Last updated: 2011-02-02Bibliographically approved

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Andersson, Pher G
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Department of Biochemistry and Organic Chemistry
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Tetrahedron: asymmetry
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