Resonant Inelastic Scattering Spectra of Free Molecules with Vibrational Resolution
2010 (English)In: Physical Review Letters, ISSN 0031-9007, Vol. 104, no 19, 193002- p.Article in journal (Refereed) Published
Inelastic x-ray scattering spectra excited at the 1s(-1) pi* resonance of gas phase O-2 have been recorded with an overall energy resolution that allows for well-resolved vibrational progressions. The nuclear wave packet dynamics in the intermediate state is reflected in vibrational excitations of the electronic ground state, and by fine-tuning the excitation energy the dissociation dynamics in the predissociative B' (3) Pi(g) final state is controlled.
Place, publisher, year, edition, pages
2010. Vol. 104, no 19, 193002- p.
IdentifiersURN: urn:nbn:se:uu:diva-136431DOI: 10.1103/PhysRevLett.104.193002ISI: 000277699600016OAI: oai:DiVA.org:uu-136431DiVA: diva2:376923