uu.seUppsala University Publications
Change search
ReferencesLink to record
Permanent link

Direct link
Direct synthesis of an heterometallic {(Mn3Cr4III)-Cr-II} wheel by decomposition of Reineckes salt
Show others and affiliations
2010 (English)In: Dalton Transactions, ISSN 1477-9226, E-ISSN 1477-9234, Vol. 39, no 9, 2344-2349 p.Article in journal (Refereed) Published
Abstract [en]

A new heterometallic Mn/Cr molecular wheel complex has been synthesized using zerovalent manganese, Reineckes salt, ammonium thiocyanate and triethanolamine (H(3)tea) as starting materials. The compound [Mn3Cr4(NCS)(6)(Htea)(6)] (1) has been characterized in terms of its electrochemical, IR and EPR spectroscopic as well as its magnetic properties. The magnetic susceptibility and magnetization data were treated simultaneously during the optimization routine and resulted in J(Mn-Cr) = + 0.43 cm(-1), J(Cr-Cr) = -4.75 cm(-1), J(Mn-Mn) = +1.78 cm(-1), g(eff) = 1.878 with the ground state S = 15/2.

Place, publisher, year, edition, pages
2010. Vol. 39, no 9, 2344-2349 p.
National Category
Chemical Sciences
URN: urn:nbn:se:uu:diva-136312DOI: 10.1039/b920375cISI: 000274580800022OAI: oai:DiVA.org:uu-136312DiVA: diva2:377091
Available from: 2010-12-13 Created: 2010-12-11 Last updated: 2016-04-22Bibliographically approved

Open Access in DiVA

No full text

Other links

Publisher's full text

Search in DiVA

By author/editor
Huang, PingStyring, Stenbjörn
By organisation
Molecular Biomimetics
In the same journal
Dalton Transactions
Chemical Sciences

Search outside of DiVA

GoogleGoogle Scholar
The number of downloads is the sum of all downloads of full texts. It may include eg previous versions that are now no longer available

Altmetric score

Total: 417 hits
ReferencesLink to record
Permanent link

Direct link