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Local structural properties of 0.5BiMnO(3)-0.5ATiO(3) (A = Ba or Sr)
Uppsala University, Disciplinary Domain of Science and Technology, Technology, Department of Engineering Sciences, Solid State Physics.
2010 (English)In: Chemical Communications, ISSN 1359-7345, E-ISSN 1364-548X, Vol. 46, no 9, 1455-1457 p.Article in journal (Refereed) Published
Abstract [en]

Neutron total scattering data have been used to probe the long-and short-range structure of 0.5BiMnO(3)-0.5ATiO(3) (A = Ba or Sr). Modelling of the total scattering data, using the reverse Monte Carlo (RMC) method, reveals local disorder that differs substantially from the average structure. Significantly, the Bi3+ cations prefer to adopt an asymmetric coordination due to the influence of the lone-pair electrons.

Place, publisher, year, edition, pages
2010. Vol. 46, no 9, 1455-1457 p.
National Category
Chemical Sciences Engineering and Technology
Research subject
Engineering Science with specialization in Solid State Physics
URN: urn:nbn:se:uu:diva-137274DOI: 10.1039/b912519aISI: 000274580700020OAI: oai:DiVA.org:uu-137274DiVA: diva2:378019
Available from: 2010-12-15 Created: 2010-12-15 Last updated: 2014-12-10Bibliographically approved

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Mathieu, Roland
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