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Extension of the charge separated-state lifetime by supramolecular association of a tetrathiafulvalene electron donor to a zinc/gold bisporphyrin
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2010 (English)In: Dalton Transactions, ISSN 1477-9226, E-ISSN 1477-9234, Vol. 39, no 6, 1450-1452 p.Article in journal (Refereed) Published
Abstract [en]

Supramolecular triads were prepared by self-assembly of 4'-pyridyl-2-tetrathiafulvalene axially bound on ZnP-spacer-AuP+ dyads; the lifetime of the charge separated state (+TTF-ZnP-Spacer-AuP center dot) formed upon light excitation of the triad is greatly increased with respect to that found in the parent dyad.

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2010. Vol. 39, no 6, 1450-1452 p.
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Natural Sciences
URN: urn:nbn:se:uu:diva-137415DOI: 10.1039/b920079gISI: 000273961100006OAI: oai:DiVA.org:uu-137415DiVA: diva2:378087
Available from: 2010-12-15 Created: 2010-12-15 Last updated: 2011-01-10Bibliographically approved

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