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Phosphaalkenes in pi-conjugation with Acetylenic Arenes
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Photochemistry and Molecular Science, Molecular Biomimetics.
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Photochemistry and Molecular Science, Molecular Biomimetics.
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Photochemistry and Molecular Science, Molecular Biomimetics.
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Photochemistry and Molecular Science, Molecular Biomimetics.
2010 (English)In: Organic Letters, ISSN 1523-7060, E-ISSN 1523-7052, Vol. 12, no 4, 692-695 p.Article in journal (Refereed) Published
Abstract [en]

Phosphaalkene inclusion at the periphery of acetylenic arenes results in decreased band gaps of the title compounds as verified by spectroscopic and electrochemical techniques. The electronic coupling between two 1-phosphahex-l-ene-3,5-diyne units is mediated by all paral-substituted arenes and Increases from 4b to 4d.

Place, publisher, year, edition, pages
2010. Vol. 12, no 4, 692-695 p.
National Category
Chemical Sciences
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URN: urn:nbn:se:uu:diva-137553DOI: 10.1021/ol902688nISI: 000274465900012OAI: oai:DiVA.org:uu-137553DiVA: diva2:378481
Available from: 2010-12-15 Created: 2010-12-15 Last updated: 2017-12-11Bibliographically approved

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