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Influence of the A cation on the low-temperature antiferromagnetism of ordered antiferroelectric A(2)CoTeO(6) perovskites
Uppsala University, Disciplinary Domain of Science and Technology, Technology, Department of Engineering Sciences, Solid State Physics.
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Materials Chemistry, Structural Chemistry.
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Materials Chemistry, Structural Chemistry.
Uppsala University, Disciplinary Domain of Science and Technology, Technology, Department of Engineering Sciences, Solid State Physics.
2011 (English)In: Physical Review B. Condensed Matter and Materials Physics, ISSN 1098-0121, E-ISSN 1550-235X, Vol. 83, no 17, 174420- p.Article in journal (Refereed) Published
Abstract [en]

We have investigated the structural and magnetic properties of antiferroelectric A(2)CoTeO(6) perovskites with A = Cd, Ca, Sr, Pb, and Ba. All compounds are antiferromagnetic at low temperatures, with the antiferromagnetic transition temperature slightly decreasing with decreasing ionic size of the A cation. Such a decrease in antiferromagnetic interaction is not observed in A(2)(2+)CoM(6+)O(6) materials with other M6+ cations of similar ionic sizes, suggesting that Te6+ cations affect the electronic and in turn the magnetic structure of the system.

Place, publisher, year, edition, pages
2011. Vol. 83, no 17, 174420- p.
National Category
Engineering and Technology Inorganic Chemistry
Research subject
Chemistry with specialization in Inorganic Chemistry; Engineering Science with specialization in Solid State Physics
Identifiers
URN: urn:nbn:se:uu:diva-139597DOI: 10.1103/PhysRevB.83.174420ISI: 000290385200004OAI: oai:DiVA.org:uu-139597DiVA: diva2:381727
Available from: 2010-12-28 Created: 2010-12-28 Last updated: 2017-12-11

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Mathieu, RolandNordblad, Per

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