Structural Assignment of σ-π-Palladium Complexes by 2D NMR
1993 (English)In: Magnetic Resonance in Chemistry, ISSN 0749-1581, E-ISSN 1097-458X, Vol. 31, no 10, 954-959 p.Article in journal (Refereed) Published
A series of (σ-π)palladium complexes derived from cyclooctadiene were investigated by 1H, 13C and 19F NMR. The stereochemical assignment was based on intramolecular NOEs in conjunction with molecular modelling and semi-empirical methods, and confirmed by interligand NOEs in nitrogen chelate complexes derived from the title compounds. The nitrogen chelating ligands are involved in a rotation with respect to the ligand-palladium axis.
Place, publisher, year, edition, pages
1993. Vol. 31, no 10, 954-959 p.
IdentifiersURN: urn:nbn:se:uu:diva-140709DOI: 10.1002/mrc.1260311014OAI: oai:DiVA.org:uu-140709DiVA: diva2:384248