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Structural Assignment of  σ-π-Palladium Complexes by 2D NMR
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Biochemistry and Organic Chemistry, Organic Chemistry.
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Biochemistry and Organic Chemistry, Organic Chemistry.
1993 (English)In: Magnetic Resonance in Chemistry, ISSN 0749-1581, E-ISSN 1097-458X, Vol. 31, no 10, 954-959 p.Article in journal (Refereed) Published
Abstract [en]

A series of (σ-π)palladium complexes derived from cyclooctadiene were investigated by 1H, 13C and 19F NMR. The stereochemical assignment was based on intramolecular NOEs in conjunction with molecular modelling and semi-empirical methods, and confirmed by interligand NOEs in nitrogen chelate complexes derived from the title compounds. The nitrogen chelating ligands are involved in a rotation with respect to the ligand-palladium axis.

Place, publisher, year, edition, pages
1993. Vol. 31, no 10, 954-959 p.
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Natural Sciences
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URN: urn:nbn:se:uu:diva-140709DOI: 10.1002/mrc.1260311014OAI: oai:DiVA.org:uu-140709DiVA: diva2:384248
Available from: 2011-01-08 Created: 2011-01-08 Last updated: 2012-01-26Bibliographically approved

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Gogoll, AdolfGrennberg, Helena

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