Transmetalation with Pd(II) of an Organomercurial Arising from the Hg(II)‑Mediated Cyclopropane Cleavage: Tuning of the Reactivity by Ligands and a Novel, Intramolecular Redox Reaction
1992 (English)In: Journal of the Chemical Society, Chemical Communications, ISSN 0022-4936, Vol. 15, 1086-1087 p.Article in journal (Refereed) Published
The cleavage of the fused-ring cyclopropane hydroxy derivative 1 by means of HgII is highly stereoselective and gives a rearranged organomercurial 3, transmetallation of which with PdII can be controlled by ligands to afford either lactol 4 or acid 8; the latter compound is formed via an intramolecular insertion of Pd into the C–H bond (6→7), as evidenced by isotopic labelling.
Place, publisher, year, edition, pages
1992. Vol. 15, 1086-1087 p.
IdentifiersURN: urn:nbn:se:uu:diva-140718DOI: 10.1039/C39920001086OAI: oai:DiVA.org:uu-140718DiVA: diva2:384256