Complete 1H and 13C NMR spectral assignment of venturicidin A by 2D NMR spectroscopy
1989 (English)In: Magnetic Resonance in Chemistry, ISSN 0749-1581, E-ISSN 1097-458X, Vol. 27, no 9, 863-871 p.Article in journal (Refereed) Published
After correlation of the majority of signals by COSY and one-bond heteronuclear correlation, the complete assignment of the 1H and 13C NMR spectra of the macrolide antibiotic venturicidin A required the application of long-range CH coupling information. This was accessible by the COLOC-S and selective INEPT experiments, and the sensitivity of these experiments is discussed. Steric information was obtained from a NOESY spectrum, and the solution structure compared with that in the crystal.
Place, publisher, year, edition, pages
1989. Vol. 27, no 9, 863-871 p.
Medical and Health Sciences
IdentifiersURN: urn:nbn:se:uu:diva-140733DOI: 10.1002/mrc.1260270909OAI: oai:DiVA.org:uu-140733DiVA: diva2:384270