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Exploring the substrate scope of the Ru(II)-catalyzed kharasch reaction
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Biochemistry and Organic Chemistry.
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Biochemistry and Organic Chemistry.
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Biochemistry and Organic Chemistry.
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Biochemistry and Organic Chemistry.
2007 (English)In: Collection of Czechoslovak Chemical Communications, ISSN 0010-0765, E-ISSN 1212-6950, Vol. 72, no 8, 1005-1013 p.Article in journal (Refereed) Published
Abstract [en]

The Kharasch reaction, or atom-transfer addition of polyhalogenated alkanes to alkenes is known to be catalyzed by a number of Ru( II) complexes. The easily prepared [ RuCl2( PPh3)(3)] was used to investigate the reaction scope. A number of halogenated alkanes were added to a range of alkenes with good to excellent regioselectivities.

Place, publisher, year, edition, pages
2007. Vol. 72, no 8, 1005-1013 p.
National Category
Chemical Sciences
Identifiers
URN: urn:nbn:se:uu:diva-143838DOI: 10.1135/cccc20071005ISI: 000249136800003OAI: oai:DiVA.org:uu-143838DiVA: diva2:391863
Available from: 2011-01-25 Created: 2011-01-25 Last updated: 2017-12-11Bibliographically approved

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Department of Biochemistry and Organic Chemistry
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Chemical Sciences

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