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Fragmentation of methyl chloride studied by partial positive and negative ion-yield spectroscopy
Uppsala University, Disciplinary Domain of Science and Technology, Physics, Department of Physics, Physics V.
Uppsala University, Disciplinary Domain of Science and Technology, Physics, Department of Physics, Physics V.
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2007 (English)In: Journal of Chemical Physics, ISSN 0021-9606, E-ISSN 1089-7690, Vol. 126, no 8, 084309- p.Article in journal (Refereed) Published
Abstract [en]

The authors present partial-ion-yield experiments on the methyl chloride molecule excited in the vicinity of the C12p and C1s inner shells. A large number of fragments, cations produced by dissociation or recombination processes, as well as anionic species, have been detected. Although the spectra exhibit different intensity distributions depending on the core-excited atom, general observations include strong site-selective fragmentation along the C-Cl bond axis and a strong intensity dependence of transitions involving Rydberg series on fragment size.

Place, publisher, year, edition, pages
2007. Vol. 126, no 8, 084309- p.
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Physical Sciences
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URN: urn:nbn:se:uu:diva-145770DOI: 10.1063/1.2464093ISI: 000244530900018OAI: oai:DiVA.org:uu-145770DiVA: diva2:396798
Available from: 2011-02-11 Created: 2011-02-11 Last updated: 2017-12-11Bibliographically approved

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