Symmetry and vibrationally resolved absorption spectra near the OK edge of N2O: Experiment and theory
2007 (English)In: Chemical Physics Letters, ISSN 0009-2614, E-ISSN 1873-4448, Vol. 435, no 4-6, 182-187 p.Article in journal (Refereed) Published
Angle-resolved energetic-ion yield spectra have been measured in the 0 Is excitation region of N2O. Franck-Condon analysis based on ab initio two-dimensional potential energy surfaces of the core-excited Rydberg states reproduces well the observed vibrational excitations specific to the individual Rydberg states. The irregular Rydberg behavior in the Sigma-symmetry absorption spectrum is attributed the valence-Rydberg coupling in light of the second moment analysis.
Place, publisher, year, edition, pages
2007. Vol. 435, no 4-6, 182-187 p.
IdentifiersURN: urn:nbn:se:uu:diva-145837DOI: 10.1016/j.cplett.2006.12.071ISI: 000244474900003OAI: oai:DiVA.org:uu-145837DiVA: diva2:397037