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Symmetry and vibrationally resolved absorption spectra near the OK edge of N2O: Experiment and theory
Uppsala University, Disciplinary Domain of Science and Technology, Physics, Department of Physics, Physics II.
Uppsala University, Disciplinary Domain of Science and Technology, Physics, Department of Physics, Physics II.
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2007 (English)In: Chemical Physics Letters, ISSN 0009-2614, E-ISSN 1873-4448, Vol. 435, no 4-6, 182-187 p.Article in journal (Refereed) Published
Abstract [en]

Angle-resolved energetic-ion yield spectra have been measured in the 0 Is excitation region of N2O. Franck-Condon analysis based on ab initio two-dimensional potential energy surfaces of the core-excited Rydberg states reproduces well the observed vibrational excitations specific to the individual Rydberg states. The irregular Rydberg behavior in the Sigma-symmetry absorption spectrum is attributed the valence-Rydberg coupling in light of the second moment analysis.

Place, publisher, year, edition, pages
2007. Vol. 435, no 4-6, 182-187 p.
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Physical Sciences
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URN: urn:nbn:se:uu:diva-145837DOI: 10.1016/j.cplett.2006.12.071ISI: 000244474900003OAI: oai:DiVA.org:uu-145837DiVA: diva2:397037
Available from: 2011-02-11 Created: 2011-02-11 Last updated: 2017-12-11Bibliographically approved

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