uu.seUppsala University Publications
Change search
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • ieee
  • modern-language-association
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf
Selective vibrational excitation in the resonant Auger decay following core-to-pi transitions in N2O
Uppsala University, Disciplinary Domain of Science and Technology, Physics, Department of Physics and Astronomy, Surface and Interface Science.
Uppsala University, Disciplinary Domain of Science and Technology, Physics, Department of Physics and Astronomy, Surface and Interface Science.
Show others and affiliations
2010 (English)In: Journal of Electron Spectroscopy and Related Phenomena, ISSN 0368-2048, E-ISSN 1873-2526, Vol. 181, no 2-3, 129-134 p.Article in journal (Refereed) Published
Abstract [en]

In N2O a detailed study of the vibrational distribution of the (X) over tilde state reached after decay of core-to-pi* excitation of N terminal, N central and 0 1s core levels is reported. We observe a change in the relative intensity of bending versus stretching modes while scanning the photon energy across all three resonances. While this effect is known to be due to the Renner-Teller splitting in the core-excited states, we could derive that the antisymmetric stretching is excited mainly in the decay of the N terminal 1s-to-pi* excitation. An explanation for such selectivity is provided in terms of interplay of vibrational structure on potential energy surfaces of different electronic states involved in the process.

Place, publisher, year, edition, pages
2010. Vol. 181, no 2-3, 129-134 p.
Keyword [en]
Resonant Auger, Renner-Teller effect, Core excitation, Electron spectroscopy, N2O
National Category
Natural Sciences
Identifiers
URN: urn:nbn:se:uu:diva-147184DOI: 10.1016/j.elspec.2010.05.006ISI: 000281932100007OAI: oai:DiVA.org:uu-147184DiVA: diva2:400072
Available from: 2011-02-24 Created: 2011-02-24 Last updated: 2017-12-11Bibliographically approved

Open Access in DiVA

No full text

Other links

Publisher's full text
By organisation
Surface and Interface Science
In the same journal
Journal of Electron Spectroscopy and Related Phenomena
Natural Sciences

Search outside of DiVA

GoogleGoogle Scholar

doi
urn-nbn

Altmetric score

doi
urn-nbn
Total: 572 hits
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • ieee
  • modern-language-association
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf