Microwave-Assisted Asymmetric Intermolecular Heck Reaction using Phosphine-Thiazole Ligands
2007 (English)In: Advanced Synthesis and Catalysis, ISSN 1615-4150, Vol. 349, no 7-18, 2595-2602 p.Article in journal (Refereed) Published
A series of new phosphine-thiazole compounds has been synthesized and used as efficient ligands in the palladium-catalyzed asymmetric intermolecular Heck coupling of 2,3-dihydrofuran with aryl triflates and cyclohexenyl triflate. Microwave heating was used to accelerate the reactions and gave complete conversions in as little as one hour. Products were obtained with good to excellent enantioselectivities.
Place, publisher, year, edition, pages
2007. Vol. 349, no 7-18, 2595-2602 p.
asymmetric catalysis, Heck reaction, microwave heating, phosphine-thiazole ligands
IdentifiersURN: urn:nbn:se:uu:diva-12345DOI: 10.1002/adsc.200700390OAI: oai:DiVA.org:uu-12345DiVA: diva2:40114