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Asymmetric Hydrogenation of Minimally Functionalised Terminal Olefins: An Alternative Sustainable and Direct Strategy for Preparing Enantioenriched Hydrocarbons
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Biochemistry and Organic Chemistry, Organic Chemistry.
2010 (English)In: Chemistry - A European Journal, ISSN 0947-6539, E-ISSN 1521-3765, Vol. 16, no 48, 14232-14240 p.Article, review/survey (Refereed) Published
Abstract [en]

This account discusses the progress made in the asymmetric hydrogenation of minimally functionalised terminal olefins as a new, alternative, sustainable and direct strategy for preparing enantioenriched hydrocarbons. It discusses the latest development in catalyst design, from the initial discovery of lanthanide catalytic precursors, through the use of transition-metal/diphosphine iminophosphorane precursors, to the successful iridium/P,N catalytic systems.

Place, publisher, year, edition, pages
2010. Vol. 16, no 48, 14232-14240 p.
Keyword [en]
carbene ligands, hydrogenation, iridium, olefins, P ligands
National Category
Chemical Sciences
URN: urn:nbn:se:uu:diva-148143DOI: 10.1002/chem.201001909ISI: 000286484800005PubMedID: 21140401OAI: oai:DiVA.org:uu-148143DiVA: diva2:401429
Available from: 2011-03-02 Created: 2011-03-02 Last updated: 2011-03-02Bibliographically approved

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