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Synthesis of estradiol backbone mimics via the Stille reaction using copper(II) oxide as co-reagent
Uppsala University, Disciplinary Domain of Medicine and Pharmacy, Faculty of Pharmacy, Department of Medicinal Chemistry, Organic Pharmaceutical Chemistry.
2011 (English)In: Tetrahedron Letters, ISSN 0040-4039, E-ISSN 1359-8562, Vol. 52, no 2, 209-211 p.Article in journal (Refereed) Published
Abstract [en]

Sterically hindered biaryls and 2-phenylbenzo[b]thiophenes that can serve as templates for mimics of the estradiol backbone were prepared in modest to good yields by the Stille reaction using CuO as a co-reagent. Due to the neutral conditions applied in the Stille reaction, protection strategies were unnecessary for hydroxy containing coupling partners. Ligandless coupling conditions were also evaluated.

Place, publisher, year, edition, pages
2011. Vol. 52, no 2, 209-211 p.
National Category
Organic Chemistry
Identifiers
URN: urn:nbn:se:uu:diva-148465DOI: 10.1016/j.tetlet.2010.10.144ISI: 000286789300010OAI: oai:DiVA.org:uu-148465DiVA: diva2:402355
Available from: 2011-03-08 Created: 2011-03-07 Last updated: 2017-12-11Bibliographically approved

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