Effect of the Cl2p core orbital excitation on the nuclear dynamics of the three dichloroethylene isomers
2011 (English)In: Journal of Electron Spectroscopy and Related Phenomena, ISSN 0368-2048, Vol. 184, no 1-2, 24-28 p.Article in journal (Refereed) Published
In this article, we present the X-ray absorption spectra of the three isomers of dichloroethylene C2H2Cl2 in the vicinity of the chlorine L-2 and L-3 edges. These isomers were excited along the first Cl2p to lowest unoccupied molecular orbital transition and an analysis of the corresponding resonant Auger spectra shows that the C-Cl bond can break before the electronic decay. An investigation of a possible Auger Doppler-like effect is also presented.
Place, publisher, year, edition, pages
2011. Vol. 184, no 1-2, 24-28 p.
X-ray absorption, Resonant Auger decay, Ultrafast dynamics, Isomer, Doppler-effect
IdentifiersURN: urn:nbn:se:uu:diva-151975DOI: 10.1016/j.elspec.2010.11.002ISI: 000289015400005OAI: oai:DiVA.org:uu-151975DiVA: diva2:411954