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Effect of the Cl2p core orbital excitation on the nuclear dynamics of the three dichloroethylene isomers
Uppsala University, Disciplinary Domain of Science and Technology, Physics, Department of Physics and Astronomy, Surface and Interface Science.
Uppsala University, Disciplinary Domain of Science and Technology, Physics, Department of Physics and Astronomy, Surface and Interface Science.
Uppsala University, Disciplinary Domain of Science and Technology, Physics, Department of Physics and Astronomy, Surface and Interface Science.
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2011 (English)In: Journal of Electron Spectroscopy and Related Phenomena, ISSN 0368-2048, E-ISSN 1873-2526, Vol. 184, no 1-2, 24-28 p.Article in journal (Refereed) Published
Abstract [en]

In this article, we present the X-ray absorption spectra of the three isomers of dichloroethylene C2H2Cl2 in the vicinity of the chlorine L-2 and L-3 edges. These isomers were excited along the first Cl2p to lowest unoccupied molecular orbital transition and an analysis of the corresponding resonant Auger spectra shows that the C-Cl bond can break before the electronic decay. An investigation of a possible Auger Doppler-like effect is also presented.

Place, publisher, year, edition, pages
2011. Vol. 184, no 1-2, 24-28 p.
Keyword [en]
X-ray absorption, Resonant Auger decay, Ultrafast dynamics, Isomer, Doppler-effect
National Category
Physical Sciences
Identifiers
URN: urn:nbn:se:uu:diva-151975DOI: 10.1016/j.elspec.2010.11.002ISI: 000289015400005OAI: oai:DiVA.org:uu-151975DiVA: diva2:411954
Available from: 2011-04-20 Created: 2011-04-20 Last updated: 2017-12-11Bibliographically approved

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