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Crystal and magnetic structure of TbNiSnD studied by neutron powder diffraction
Uppsala University, Disciplinary Domain of Science and Technology, För teknisk-naturvetenskapliga fakulteten gemensamma enheter, The Studsvik Neutron Research Laboratory.
Laboratoire de Crystallographie du CNRS.
Uppsala University, Disciplinary Domain of Science and Technology, För teknisk-naturvetenskapliga fakulteten gemensamma enheter, The Studsvik Neutron Research Laboratory.
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2007 (English)In: Journal of Magnetism and Magnetic Materials, ISSN 0304-8853, E-ISSN 1873-4766, Vol. 311, no 2, 639-643 p.Article in journal (Refereed) Published
Abstract [en]

The crystal and magnetic structure of TbNiSnD has been studied by neutron powder diffraction. The deuteride crystallizes with the filled TiNiSi type structure (sp. gr. Pnma; a=7.0354(1); b=4.20662(9); c=8.1808(2) Å at 293 K; a=7.008(1); b=4.1954(6); c=8.153(1) Å at 2 K) and is canted ferromagnetic below 10 K. The deuterium atoms occupy the tetrahedral Tb3Ni sites. The Tb atoms carry a magnetic moment of 6.6(1) μB /Tb. They order antiferromagnetically along the a-axis and ferromagnetically along the c-axis. No significant magnetic moment on the Ni atoms has been observed by neutron diffraction. Insertion of deuterium in TbNiSn induces both a change of the magnetic structure and a reduction of the Tb magnitude of the magnetic moment.

Place, publisher, year, edition, pages
2007. Vol. 311, no 2, 639-643 p.
Keyword [en]
Neutron diffraction, Magnetic structure, Metal hydrides, Terbium
National Category
Natural Sciences Engineering and Technology
Identifiers
URN: urn:nbn:se:uu:diva-14881DOI: 10.1016/j.jmmm.2006.08.043ISI: 000245495700026OAI: oai:DiVA.org:uu-14881DiVA: diva2:42652
Available from: 2008-01-31 Created: 2008-01-31 Last updated: 2017-12-11Bibliographically approved

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Svedlindh, Peter

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