Spectroscopically characterized intermediates of catalytic H2 formation by [FeFe] hydrogenase models
2011 (English)In: Energy & Environmental Science, ISSN 1754-5692, E-ISSN 1754-5706, Vol. 4, no 7, 2340-2352 p.Article, review/survey (Refereed) Published
This review compiles species that are known or potential intermediates in the catalytic formation of H-2 by diiron dithiolate complexes inspired by the active site of the [FeFe] hydrogenases. The data collection emphasizes spectroscopic characteristics (NMR, IR, UV-Vis, EPR) of protonated and reduced derivatives of the iron complexes that could provide reference data to the identification of intermediates in mechanistic studies.
Place, publisher, year, edition, pages
2011. Vol. 4, no 7, 2340-2352 p.
IdentifiersURN: urn:nbn:se:uu:diva-156419DOI: 10.1039/c0ee00708kISI: 000292205100002OAI: oai:DiVA.org:uu-156419DiVA: diva2:431516