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Spectroscopically characterized intermediates of catalytic H2 formation by [FeFe] hydrogenase models
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Photochemistry and Molecular Science, Chemical Physics.
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Photochemistry and Molecular Science, Molecular Biomimetics.
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Photochemistry and Molecular Science, Chemical Physics.
2011 (English)In: Energy & Environmental Science, ISSN 1754-5692, E-ISSN 1754-5706, Vol. 4, no 7, 2340-2352 p.Article, review/survey (Refereed) Published
Abstract [en]

This review compiles species that are known or potential intermediates in the catalytic formation of H-2 by diiron dithiolate complexes inspired by the active site of the [FeFe] hydrogenases. The data collection emphasizes spectroscopic characteristics (NMR, IR, UV-Vis, EPR) of protonated and reduced derivatives of the iron complexes that could provide reference data to the identification of intermediates in mechanistic studies.

Place, publisher, year, edition, pages
2011. Vol. 4, no 7, 2340-2352 p.
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Natural Sciences
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URN: urn:nbn:se:uu:diva-156419DOI: 10.1039/c0ee00708kISI: 000292205100002OAI: oai:DiVA.org:uu-156419DiVA: diva2:431516
Available from: 2011-07-20 Created: 2011-07-20 Last updated: 2017-12-08

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Ott, SaschaLomoth, Reiner

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