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Light-Induced Water Oxidation by a Ru complex Containing a Bio-Inspired Ligand
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2011 (English)In: Chemistry - A European Journal, ISSN 0947-6539, E-ISSN 1521-3765, Vol. 17, no 28, 7953-7959 p.Article in journal (Refereed) Published
Abstract [en]

The new Ru complex 8 containing the bio-inspired ligand 7 was successfully synthesized and characterized. Complex 8 efficiently catalyzes water oxidation using Ce(IV) and Ru(III) as chemical oxidants. More importantly, this complex has a sufficiently low overpotential to utilize ruthenium polypyridyl-type complexes as photosensitizers.

Place, publisher, year, edition, pages
2011. Vol. 17, no 28, 7953-7959 p.
Keyword [en]
homogeneous catalysis, oxidation, photochemistry, ruthenium, water splitting
National Category
Natural Sciences
Identifiers
URN: urn:nbn:se:uu:diva-157268DOI: 10.1002/chem.201003702ISI: 000293383300033OAI: oai:DiVA.org:uu-157268DiVA: diva2:435948
Available from: 2011-08-22 Created: 2011-08-22 Last updated: 2017-12-08Bibliographically approved

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