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The Synthesis of Chiral Periodic Organosilica Materials with Ultrasmall Mesopores
Queen's University, Department of Chemistry, Kingston, ON, Kanada.
Queen's University, Department of Chemistry, Kingston, ON, Kanada.
Queen's University, Department of Chemistry, Kingston, ON, Kanada.
Uppsala University, Disciplinary Domain of Science and Technology, Technology, Department of Engineering Sciences, Nanotechnology and Functional Materials.
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2011 (English)In: Angewandte Chemie International Edition, ISSN 1433-7851, E-ISSN 1521-3773, Vol. 50, no 35, 8095-8099 p.Article in journal (Refereed) Published
Abstract [en]

Helical organosilica materials were synthesized for the first time using a novel binaphthyl-based chiral co-monomer in less than 1 hour. The incorporation of a chiral co-monomer in the wall was shown to influence the curvature of the helical materials. As the amount of the chiral co-monomer was increased, the degree of curvature increased, illustrating the importance of this monomer to the overall morphology.

Place, publisher, year, edition, pages
2011. Vol. 50, no 35, 8095-8099 p.
Keyword [en]
chirality, helical structures, microporous materials, organosilica, silicon
National Category
Chemical Sciences Nano Technology
Research subject
Engineering Science with specialization in Nanotechnology and Functional Materials
Identifiers
URN: urn:nbn:se:uu:diva-158666DOI: 10.1002/anie.201101909ISI: 000294177500024PubMedID: 21755582OAI: oai:DiVA.org:uu-158666DiVA: diva2:440641
Available from: 2011-09-13 Created: 2011-09-13 Last updated: 2017-12-08Bibliographically approved

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Garcia-Bennett, Alfonso E.

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