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Synthesis of barettin
Uppsala University, Disciplinary Domain of Medicine and Pharmacy, Faculty of Pharmacy, Department of Medicinal Chemistry, Division of Pharmacognosy.
Uppsala University, Disciplinary Domain of Medicine and Pharmacy, Faculty of Pharmacy, Department of Medicinal Chemistry, Division of Pharmacognosy.
2004 (English)In: Tetrahedron, ISSN 0040-4020, E-ISSN 1464-5416, Vol. 60, no 4, 961-965 p.Article in journal (Refereed) Published
Abstract [en]

The indole alkaloid barettin (with bromine in 6-position), isolated from the marine sponge Geodia Barretti, has been synthesised via a Horner-Wadsworth-Emmons type reaction from 6-bromoindole-3-carboxaldehyde to introduce the dehydro-functionality. Subsequent deprotection and cyclisation afforded the natural product in Z-conformation.

Place, publisher, year, edition, pages
2004. Vol. 60, no 4, 961-965 p.
Keyword [en]
Geodia barretti, barettin, N-boc protection of arginine, HWE-reaction
National Category
Chemical Sciences Pharmaceutical Sciences
Identifiers
URN: urn:nbn:se:uu:diva-16362DOI: 10.1016/j.tet.2003.11.031ISI: 000188227400018OAI: oai:DiVA.org:uu-16362DiVA: diva2:44133
Available from: 2008-05-20 Created: 2008-05-20 Last updated: 2017-12-08Bibliographically approved

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Sjögren, MartinBohlin, Lars

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